Defect structure of nonstoichiometric perovskite

The Po 2 dependance on electrical conductivity and the oxygen diffusion in non-stoichiometric BaTiO 3 and (Ba, Ca) TiO 3 ceramics were investigated. It is confirmed that the electrical conductivity of A-site-excess specimen at high temperature is decreasing with decrease of oxygen pressure. The mech...

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Veröffentlicht in:Japanese Journal of Applied Physics 1989, Vol.28 (S2), p.52-55
Hauptverfasser: KONDOU, H, FUJIMOTO, M, HANEDA, H, SHIRASAKI, S
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Sprache:eng
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Zusammenfassung:The Po 2 dependance on electrical conductivity and the oxygen diffusion in non-stoichiometric BaTiO 3 and (Ba, Ca) TiO 3 ceramics were investigated. It is confirmed that the electrical conductivity of A-site-excess specimen at high temperature is decreasing with decrease of oxygen pressure. The mechanism is discussed with the oxygen defect structure, defect structure, barium titanate, calcium doping, Semi-conductor, nonstoichiometry, electrical conductivity, oxygen diffusivity.
ISSN:0021-4922
1347-4065
DOI:10.7567/jjaps.28s2.52