Photoluminescence of Eu 3+ in Layered A 2 B 2 O 7 Ferroelectric Crystals

The excitation and emission spectra of Eu 3+ in the ferroelectric Sr 2 Ta 2 O 7 , Sr 2 Nb 2 O 7 and La 2 Ti 2 O 7 have been measured. The crystal field symmetry around the Eu 3+ is discussed in connection with the layered perovskite structure of these oxides. It has been found that the 5 D 0 - 7 F 2...

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Veröffentlicht in:Japanese Journal of Applied Physics 1985-01, Vol.24 (S2), p.662
Hauptverfasser: Mochida, Tetsuya, Ohi, Kikuo
Format: Artikel
Sprache:eng
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Zusammenfassung:The excitation and emission spectra of Eu 3+ in the ferroelectric Sr 2 Ta 2 O 7 , Sr 2 Nb 2 O 7 and La 2 Ti 2 O 7 have been measured. The crystal field symmetry around the Eu 3+ is discussed in connection with the layered perovskite structure of these oxides. It has been found that the 5 D 0 - 7 F 2 emission lines in Sr 2 Ta 2 O 7 :Eu 3+ and Sr 2 Nb 2 O 7 :Eu 3+ change with the structural phase transition.
ISSN:0021-4922
1347-4065
DOI:10.7567/JJAPS.24S2.662