Rhenium exchange current density and transfer coefficient in the KF-KBF4-B2O3 molten salt: Short communication

The present paper is devoted to the study of the exchange current density of Re transfer in the high-temperature molten salt system using the Tafel dependencies. This data allowed precise information on the electrochemical behavior of the reaction mechanism. The exchange current density of the redox...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of electrochemical science and engineering 2024-08
Hauptverfasser: Chernyshev, Aleksandr A., Apisarov, Alexey, Isakov, Andrey, Zaikov, Yury
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The present paper is devoted to the study of the exchange current density of Re transfer in the high-temperature molten salt system using the Tafel dependencies. This data allowed precise information on the electrochemical behavior of the reaction mechanism. The exchange current density of the redox Re0/Re7+ pair was found to be 381.27 mA cm-2 at 773 K and KReO4 concentration of 1 wt.%. The cathode transfer coefficient was calculated using the inclination angle tangent of Tafel graphs.
ISSN:1847-9286
1847-9286
DOI:10.5599/jese.2422