A Dinuclear Palladium(II) Complex of the {N(SPPh2)2}- Ligand – Synthesis and Structure

A Dinuclear Palladium(II) Complex of the {N(SPPh2)2}- Ligand – Synthesis and Structure

The synthesis and characterization including the crystal structure of the dinuclear palladium( II) complex [(k-S,S’)-{N(SPPh }Pd(m-{k -S'',S'''})-{N(SPPh }PdCl ] (1) are reported. Compound 1 was obtained from the reaction of [PdCl (COD)] (COD=1,5-cyclooctadiene) and HN(SPPh...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2013-06, Vol.68 (5), p.557-560
Hauptverfasser: Marks, Sebastian, Roesky, Peter W.
Format: Artikel
Sprache:eng
Schlagworte:
Bimetallic Complex
Palladium
PNP Ligand
S Donor Ligand
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Zusammenfassung:The synthesis and characterization including the crystal structure of the dinuclear palladium( II) complex [(k-S,S’)-{N(SPPh }Pd(m-{k -S'',S'''})-{N(SPPh }PdCl ] (1) are reported. Compound 1 was obtained from the reaction of [PdCl (COD)] (COD=1,5-cyclooctadiene) and HN(SPPh in a 1:1 molar ratio in CH Cl . The {N(SPPh ligands act both as bridging and/or terminally chelating units
ISSN:0932-0776
1865-7117
DOI:10.5560/znb.2013-3066