Theory of Voltammetric Current of Electron Transfer at Organic(O)/Aqueous(W) Solution Interface

Theory of Voltammetric Current of Electron Transfer at Organic(O)/Aqueous(W) Solution Interface

A cylindrical-diffusion model to include the bimolecular-reaction effect in voltammertric theory of the electron transfer at O/W interface is proposed. Analytical expressions for pulse-voltammetric current whenm the electron transfer is of pseudo-unimolecular nature are presented.

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Veröffentlicht in:Pōrarogurafī Review of polarography 2003/05/30, Vol.49(1), pp.31-35
1. Verfasser: Senda, Mitsugi
Format: Artikel
Sprache:eng
Schlagworte:
bimolecular reaction
electron transfer
O/W interface
voltammetry
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Zusammenfassung:A cylindrical-diffusion model to include the bimolecular-reaction effect in voltammertric theory of the electron transfer at O/W interface is proposed. Analytical expressions for pulse-voltammetric current whenm the electron transfer is of pseudo-unimolecular nature are presented.
ISSN:0034-6691
1884-7692
DOI:10.5189/revpolarography.49.31