Mutual Recognition of Enantiomers

Homochiral or heterochiral interaction of enantiomers is a fundamental principle in crystal lattice formation, giving either racemates or conglomerates, and multi-stage interactions. Such diastereomeric effects arising from labile molecular assembly are also significant in various solution-phase phe...

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Veröffentlicht in:Journal of Synthetic Organic Chemistry, Japan Japan, 1990/06/01, Vol.48(6), pp.447-456
Hauptverfasser: NOYORI, Ryoji, OKADA, Shigemitsu
Format: Artikel
Sprache:eng
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Zusammenfassung:Homochiral or heterochiral interaction of enantiomers is a fundamental principle in crystal lattice formation, giving either racemates or conglomerates, and multi-stage interactions. Such diastereomeric effects arising from labile molecular assembly are also significant in various solution-phase phenomena related to physical, spectroscopic, and chromatographic properties of chiral organic substances. The enantiomer recognition also affects the degree of stereoselection and the efficiency of chiral multiplication in stereoselective organic reactions.
ISSN:0037-9980
1883-6526
DOI:10.5059/yukigoseikyokaishi.48.447