Coordination Methods of Thioligands in Trinuclear Complexes of Platinum (II)

The trinuclear complexes with simple and mixed ligands of platinum (II) with mercaptoethanol and mercaptoethylamine have been generated and their contents and structures investigated by numerous physicochemical methods. Mercaptoethanol (SHCH2CH2OH) is coordinated monodentally with just sulfur atom and forms pentacyclic metalchelate ring, where as mercaptoethylamine (HSCH2CH2NH2) is coordinated monodentally as well as bidentally and forms an identical ring (pentacyclic metalchelate). The sulfur atom of ligands plays a bridge role between the metals in the trinuclear platinum complexes. The hydroxyl group of mercaptoethanol does not participate in the coordination