Synthesis and Application of Supramolecular Glycopolymer

Supramolecular glycopolymers are constructed by non-covalent interaction of carbohydrates monomers, which possess mechanical and self-healing properties based on the cross-linked structure derived from the non-covalent bonds. Naturally occurring cyclodextrins, cellulose, chitin, and chitosan have been used to prepare supramolecular glycopolymers. However, recent advances in synthetic methodologies for sugar molecules have led to research using chemically synthesized sugar derivatives. In this mini review, I describe the influence of chemically synthesized carbohydrates monomers structures on the structures and functions of supramolecular glycopolymers.