Dimethyl Sulfoxide-Accelerated Reductive Deamination of Aromatic Amines with T-BuONO in Tetrahydrofuran

Dimethyl Sulfoxide-Accelerated Reductive Deamination of Aromatic Amines with T-BuONO in Tetrahydrofuran

An efficient method for the conversion of aryl amines into arenes by a one-pot reductive deamination has been achieved. It was found the reductive deamination using t-BuONO in tetrahydrofuran could be accelerated by dimethyl sulfoxide and provided the deamination products with good yields under mild...

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Veröffentlicht in:Journal of chemical research 2018-11, Vol.42 (11), p.579-583
Hauptverfasser: Fang, Lu, Qi, Liang, Ye, Longfei, Pan, Zhentao, Luo, Wenjun, Ling, Fei, Zhong, Weihui
Format: Artikel
Sprache:eng
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Zusammenfassung:An efficient method for the conversion of aryl amines into arenes by a one-pot reductive deamination has been achieved. It was found the reductive deamination using t-BuONO in tetrahydrofuran could be accelerated by dimethyl sulfoxide and provided the deamination products with good yields under mild conditions. A plausible mechanism is discussed.
ISSN:1747-5198
2047-6507
DOI:10.3184/174751918X15402967122774