Comparative Evaluation of Oxidising and Nucleophilic Properties of Some α-Nucleophiles

Six α-nucleophiles were evaluated at pH = 8 in an aqueous methanolic solution for their oxidising power towards tetrahydrothiophene, and the nucleophilic properties towards paraoxon. MMPP and m-CPBA are the most versatile reagents and can act as nucleophiles as well as oxidising agents.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of chemical research 2002-07, Vol.2002 (7), p.336-338
Hauptverfasser:	Cassagne, Thierry, Cristau, Henri-Jean, Delmas, Gérard, Desgranges, Michel, Lion, Claude, Magnaud, Gilbert, Torreilles, Έliane, Virieux, David
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Six α-nucleophiles were evaluated at pH = 8 in an aqueous methanolic solution for their oxidising power towards tetrahydrothiophene, and the nucleophilic properties towards paraoxon. MMPP and m-CPBA are the most versatile reagents and can act as nucleophiles as well as oxidising agents.
ISSN:	1747-5198 2047-6507
DOI:	10.3184/030823402103172194