Lead production from recycled paste of lead acid batteries with SiC-Na2CO3
A novel pyrometallurgical route was used to reduce the lead paste to obtain metallic lead with different additions of sodium carbonate at 850°C in a silicon carbide crucible. The process allows to obtain a high recovery of metallic lead in a single step and a slag constituted mainly by lead silicate...
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Veröffentlicht in: | Russian journal of non-ferrous metals 2016-07, Vol.57 (4), p.316-324 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | A novel pyrometallurgical route was used to reduce the lead paste to obtain metallic lead with different additions of sodium carbonate at 850°C in a silicon carbide crucible. The process allows to obtain a high recovery of metallic lead in a single step and a slag constituted mainly by lead silicate. Products obtained were characterized by atomic absorption, X-ray powder diffraction and SEM-EDS techniques. A thermodynamic study was carried out with the software FactSage to determinate the compounds formation to the experimental conditions. High amounts of Na
2
CO
3
and SiC promoted the formation of a lead sulfide compound which decreased the lead recovery. |
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ISSN: | 1067-8212 1934-970X |
DOI: | 10.3103/S1067821216040118 |