Thermodynamic characteristics of the Pb-Bi alloys in the KCl-PbCl2 melt

Thermodynamic characteristics of the Pb-Bi alloys in the KCl-PbCl2 melt

The thermodynamic properties of the Pb-Bi alloys containing from 1.5 to 95 mol % Pb are investigated in a molten mixture of potassium and lead chlorides in a temperature range of 723–873 K by measuring the equilibrium values of the electromotive force. The partial and integral thermodynamic characte...

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Veröffentlicht in:Russian journal of non-ferrous metals 2011-06, Vol.52 (3), p.197-204
Hauptverfasser: Khalimullina, Yu. R., Zaikov, Yu. P., Arkhipov, P. A., Ashikhin, V. V., Skopov, G. V., Kholkina, A. S., Molchanova, N. G.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry and Materials Science
Materials Science
Metallic Materials
Metallurgy of Nonferrous Metals
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Zusammenfassung:The thermodynamic properties of the Pb-Bi alloys containing from 1.5 to 95 mol % Pb are investigated in a molten mixture of potassium and lead chlorides in a temperature range of 723–873 K by measuring the equilibrium values of the electromotive force. The partial and integral thermodynamic characteristics of the system are calculated, and its small negative deviations from ideality are established.
ISSN:1067-8212
1934-970X
DOI:10.3103/S1067821211030126