Facile preparation of Co@Co 3 O 4 @Nitrogen doped carbon composite from ionic liquid as anode material for high performance lithium-ion batteries

Co@Co 3 O 4 @Nitrogen doped carbon (Co@Co 3 O 4 @NDC) composite is synthesized by high temperature carbonization of ionic liquids followed by low temperature thermal oxidation. In the process of high temperature carbonization, cobalt ions are reduced to metallic cobalt, producing Co@Nitrogen doped carbon (Co@NDC). Co@Co 3 O 4 @NDC composite is obtained after low temperature oxidation, in which a part of the metallic cobalt is oxidized to Co 3 O 4 . The structural characterizations indicate that the composite is composed of three crystalline phases (carbon, Co and Co 3 O 4 ). The results of transmission electron microscopy study show that the carbon materials not only coat the Co@Co 3 O 4 nanoparticles, but also form carbon network that connects the Co@Co 3 O 4 nanoparticles. This conductive carbon network is beneficial to improve the electrochemical performance of the composite. The electrochemical test results show that the Co@Co 3 O 4 @NDC composite exhibits excellent electrochemical performance, delivering the discharge capacities of 790 and 304 mAh˙g −1 after 1500 cycles at 5 C and 10 C. This excellent electrochemical performance is due to synergistic effects of Co 3 O 4 , cobalt nanoparticles embedded in carbon which has high conductivity, and nitrogen functional groups.