Nitro and aminobenzimidazoles
A summary of the preparation methods of 2 tautomeric and 4 N -methylated benzimidazoles with a nitro group on the benzene ring ( 1–6 ) and with an amino group in the same positions ( 7–12 ) were summarized. Annular tautomerism of the title compounds 1–12 has been studied using 1 H, 13 C and 15 N NMR...
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Veröffentlicht in: | Acta Chimica Slovaca 2018-10, Vol.11 (2), p.182-188 |
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Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A summary of the preparation methods of 2 tautomeric and 4
N
-methylated benzimidazoles with a nitro group on the benzene ring (
1–6
) and with an amino group in the same positions (
7–12
) were summarized. Annular tautomerism of the title compounds
1–12
has been studied using
1
H,
13
C and
15
N NMR spectra in liquid and solid state (CPMAS), UV spectra and quantum chemical calculations. |
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ISSN: | 1337-978X 1337-978X |
DOI: | 10.2478/acs-2018-0026 |