Nitro and aminobenzimidazoles

A summary of the preparation methods of 2 tautomeric and 4 N -methylated benzimidazoles with a nitro group on the benzene ring ( 1–6 ) and with an amino group in the same positions ( 7–12 ) were summarized. Annular tautomerism of the title compounds 1–12 has been studied using 1 H, 13 C and 15 N NMR...

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Veröffentlicht in:Acta Chimica Slovaca 2018-10, Vol.11 (2), p.182-188
1. Verfasser: Milata, Viktor
Format: Artikel
Sprache:eng
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Zusammenfassung:A summary of the preparation methods of 2 tautomeric and 4 N -methylated benzimidazoles with a nitro group on the benzene ring ( 1–6 ) and with an amino group in the same positions ( 7–12 ) were summarized. Annular tautomerism of the title compounds 1–12 has been studied using 1 H, 13 C and 15 N NMR spectra in liquid and solid state (CPMAS), UV spectra and quantum chemical calculations.
ISSN:1337-978X
1337-978X
DOI:10.2478/acs-2018-0026