Observation of Chemical State for Interstitial Solid Solution of Carbon in Low-carbon Steel by Soft X-ray Absorption Spectroscopy

The near-edge X-ray absorption fine structure at the carbon K edge was measured for determining the chemical state of interstitial carbon in a low-carbon steel. In addition, the wavelength dependence of the photoelectron spectrum of the surface of the steel was evaluated, and a contamination and oxi...

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Veröffentlicht in:ISIJ International 2020/01/15, Vol.60(1), pp.114-119
Hauptverfasser: Ninomiya, Kakeru, Kamitani, Kazutaka, Tamenori, Yusuke, Tsuruta, Kazuki, Okajima, Toshihiro, Yoshimura, Daisuke, Sawada, Hideaki, Kinoshita, Keisuke, Nishibori, Maiko
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Sprache:eng
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Zusammenfassung:The near-edge X-ray absorption fine structure at the carbon K edge was measured for determining the chemical state of interstitial carbon in a low-carbon steel. In addition, the wavelength dependence of the photoelectron spectrum of the surface of the steel was evaluated, and a contamination and oxidation layer of 3 nm thickness was found. As a result, it was possible to observe a change in the chemical state of carbon existing in bulk iron located deeper than the oxidation and contamination layers, by evaluating the difference spectra between the sample and a reference. Furthermore, by evaluating the shape change of the difference spectra based on the heat treatment time, it was found that the chemical state of carbon in bulk iron changes with heat treatment.
ISSN:0915-1559
1347-5460
DOI:10.2355/isijinternational.ISIJINT-2019-206