Assessment of heavy metal contamination and its ecological risk in the surface sediments along the coast of Korea

Ra, K., Kim, E.-S., Kim, K.-T., Kim, J.-K., Lee, J.-M., and Choi, J.-Y., 2013. Assessment of heavy metal contamination and its ecological risk in the surface sediments along the coast of Korea. We studied the spatial distribution of heavy metal contamination and its ecological risk assessment in sediments from the Korean coast. Surface sediments collected from 12 coastal zones of Korea (total 200 sediment samples) along the west, south and east coast of Korea have been analyzed for heavy metals including Cr, Co, Ni, Cu, Zn, As, Cd, Pb and Hg using ICP-MS. Mean concentrations were 58.3 mg/kg for Cr, 10.2 mg/kg for Co, 24.3 mg/kg for Ni, 36.5 mg/kg for Cu, 122 mg/kg for Zn, 9.1 mg/kg for As, 0.25 mg/kg for Cd, 35.0 mg/kg for Pb and 0.046 mg/kg for Hg, respectively. Sediments sampled from heavily industrialized areas such as Shihwa, Masan, Gwangyang and Ulsan were highly contaminated with Cu, Zn, Cd and Hg. Significantly positive correlation among metals were observed (pHg>Cd>Zn>As>Pb>Co>Cr>Ni. Based on the comparison with sediment quality guidelines (SQGs), Cu, As and Zn levels at more than 40% of sediment samples exceeding TEL values are likely to result in potential adverse effects on sediment-dwelling organisms.