Influence of anodization time on the surface modifications on α-Fe 2 O 3 photoanode upon anodization
In searching for a suitable semiconductor material for hydrogen production via photoelectrochemical water splitting, α-Fe 2 O 3 received significant attention as a promising photoanode due to its band gap (∼2.1 eV), good stability, low cost, and natural occurrence. α-Fe 2 O 3 thin films were prepare...
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Veröffentlicht in: | Journal of materials research 2016-06, Vol.31 (11), p.1580-1587 |
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creator | Maabong, Kelebogile Hu, Yelin Braun, Artur Machatine, Augusto G.J. Diale, Mmantsae |
description | In searching for a suitable semiconductor material for hydrogen production via photoelectrochemical water splitting, α-Fe
2
O
3
received significant attention as a promising photoanode due to its band gap (∼2.1 eV), good stability, low cost, and natural occurrence. α-Fe
2
O
3
thin films were prepared by economic and facile dip coating method and subsequently subjected to an anodic potential of 700 mV versus Ag/AgCl in 1M KOH for different anodization times (1, 10, and 900 min) under illumination. X-ray diffractometry revealed increase in crystallites size from ∼31 nm for nanoparticles in pristine state to ∼38 and 44 nm after anodization for 1 and 900 min, respectively. A clear positive correlation between anodization time and grain (particle) size was observed from field emission gun scanning electron microscopy and atomic force microscopy (AFM); longer exposure time to anodizing conditions resulted in larger grains. Grain size increased from ∼57.9 nm in pristine state to ∼153.5 nm after anodization for 900 min. A significant smoothening of the surface with increase in anodization time was evident from AFM analysis. |
doi_str_mv | 10.1557/jmr.2016.53 |
format | Article |
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2
O
3
received significant attention as a promising photoanode due to its band gap (∼2.1 eV), good stability, low cost, and natural occurrence. α-Fe
2
O
3
thin films were prepared by economic and facile dip coating method and subsequently subjected to an anodic potential of 700 mV versus Ag/AgCl in 1M KOH for different anodization times (1, 10, and 900 min) under illumination. X-ray diffractometry revealed increase in crystallites size from ∼31 nm for nanoparticles in pristine state to ∼38 and 44 nm after anodization for 1 and 900 min, respectively. A clear positive correlation between anodization time and grain (particle) size was observed from field emission gun scanning electron microscopy and atomic force microscopy (AFM); longer exposure time to anodizing conditions resulted in larger grains. Grain size increased from ∼57.9 nm in pristine state to ∼153.5 nm after anodization for 900 min. A significant smoothening of the surface with increase in anodization time was evident from AFM analysis.</description><identifier>ISSN: 0884-2914</identifier><identifier>EISSN: 2044-5326</identifier><identifier>DOI: 10.1557/jmr.2016.53</identifier><language>eng</language><ispartof>Journal of materials research, 2016-06, Vol.31 (11), p.1580-1587</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c783-338c5cec9b3170d1a60e43be2c9c2119fd0809838d35375e753b243e45c7c5c93</citedby><cites>FETCH-LOGICAL-c783-338c5cec9b3170d1a60e43be2c9c2119fd0809838d35375e753b243e45c7c5c93</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Maabong, Kelebogile</creatorcontrib><creatorcontrib>Hu, Yelin</creatorcontrib><creatorcontrib>Braun, Artur</creatorcontrib><creatorcontrib>Machatine, Augusto G.J.</creatorcontrib><creatorcontrib>Diale, Mmantsae</creatorcontrib><title>Influence of anodization time on the surface modifications on α-Fe 2 O 3 photoanode upon anodization</title><title>Journal of materials research</title><description>In searching for a suitable semiconductor material for hydrogen production via photoelectrochemical water splitting, α-Fe
2
O
3
received significant attention as a promising photoanode due to its band gap (∼2.1 eV), good stability, low cost, and natural occurrence. α-Fe
2
O
3
thin films were prepared by economic and facile dip coating method and subsequently subjected to an anodic potential of 700 mV versus Ag/AgCl in 1M KOH for different anodization times (1, 10, and 900 min) under illumination. X-ray diffractometry revealed increase in crystallites size from ∼31 nm for nanoparticles in pristine state to ∼38 and 44 nm after anodization for 1 and 900 min, respectively. A clear positive correlation between anodization time and grain (particle) size was observed from field emission gun scanning electron microscopy and atomic force microscopy (AFM); longer exposure time to anodizing conditions resulted in larger grains. Grain size increased from ∼57.9 nm in pristine state to ∼153.5 nm after anodization for 900 min. A significant smoothening of the surface with increase in anodization time was evident from AFM analysis.</description><issn>0884-2914</issn><issn>2044-5326</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNpNkL1OwzAUhS0EEqEw8QLeUYLta8fOiCpKK1Xq0j1KnGs1VfMjOxngrXgRngkHGJiOdM-53_AR8shZxpXSz-fOZ4LxPFNwRRLBpEwViPyaJMwYmYqCy1tyF8KZMa6YlgnBXe8uM_YW6eBo1Q9N-1FN7dDTqe3iLeYJaZi9q-Kki7Vr7c8gLOXXZ7pBKuiBAh1PwzQsBKTzGLt_sHty46pLwIe_XJHj5vW43qb7w9tu_bJPrTaQAhirLNqiBq5Zw6ucoYQahS2s4LxwDTOsMGAaUKAVagW1kIBSWR0fC1iRp1-s9UMIHl05-rar_HvJWbkIKqOgchFUKoBvS0tZ6Q</recordid><startdate>20160614</startdate><enddate>20160614</enddate><creator>Maabong, Kelebogile</creator><creator>Hu, Yelin</creator><creator>Braun, Artur</creator><creator>Machatine, Augusto G.J.</creator><creator>Diale, Mmantsae</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160614</creationdate><title>Influence of anodization time on the surface modifications on α-Fe 2 O 3 photoanode upon anodization</title><author>Maabong, Kelebogile ; Hu, Yelin ; Braun, Artur ; Machatine, Augusto G.J. ; Diale, Mmantsae</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c783-338c5cec9b3170d1a60e43be2c9c2119fd0809838d35375e753b243e45c7c5c93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maabong, Kelebogile</creatorcontrib><creatorcontrib>Hu, Yelin</creatorcontrib><creatorcontrib>Braun, Artur</creatorcontrib><creatorcontrib>Machatine, Augusto G.J.</creatorcontrib><creatorcontrib>Diale, Mmantsae</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of materials research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maabong, Kelebogile</au><au>Hu, Yelin</au><au>Braun, Artur</au><au>Machatine, Augusto G.J.</au><au>Diale, Mmantsae</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of anodization time on the surface modifications on α-Fe 2 O 3 photoanode upon anodization</atitle><jtitle>Journal of materials research</jtitle><date>2016-06-14</date><risdate>2016</risdate><volume>31</volume><issue>11</issue><spage>1580</spage><epage>1587</epage><pages>1580-1587</pages><issn>0884-2914</issn><eissn>2044-5326</eissn><abstract>In searching for a suitable semiconductor material for hydrogen production via photoelectrochemical water splitting, α-Fe
2
O
3
received significant attention as a promising photoanode due to its band gap (∼2.1 eV), good stability, low cost, and natural occurrence. α-Fe
2
O
3
thin films were prepared by economic and facile dip coating method and subsequently subjected to an anodic potential of 700 mV versus Ag/AgCl in 1M KOH for different anodization times (1, 10, and 900 min) under illumination. X-ray diffractometry revealed increase in crystallites size from ∼31 nm for nanoparticles in pristine state to ∼38 and 44 nm after anodization for 1 and 900 min, respectively. A clear positive correlation between anodization time and grain (particle) size was observed from field emission gun scanning electron microscopy and atomic force microscopy (AFM); longer exposure time to anodizing conditions resulted in larger grains. Grain size increased from ∼57.9 nm in pristine state to ∼153.5 nm after anodization for 900 min. A significant smoothening of the surface with increase in anodization time was evident from AFM analysis.</abstract><doi>10.1557/jmr.2016.53</doi><tpages>8</tpages></addata></record> |
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title | Influence of anodization time on the surface modifications on α-Fe 2 O 3 photoanode upon anodization |
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