Helical chain Ag(I) complexes with a tridentate N-donor ligand: syntheses, structural characterization, and properties
The tridentate N-donor ligand 2,6-di(2-oxazolyl)pyridine (L) reacts with AgClO and AgPF to yield two new complexes, {[Ag (L) ](ClO ( ) and {[Ag (L) ](PF ( ), which have been characterized by single-crystal and powder X-ray diffractions, IR spectroscopy, and elemental and thermogravimetric analyses....
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2015-12, Vol.70 (12), p.851-856 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The tridentate N-donor ligand 2,6-di(2-oxazolyl)pyridine (L) reacts with AgClO
and AgPF
to yield two new complexes, {[Ag
(L)
](ClO
(
) and {[Ag
(L)
](PF
(
), which have been characterized by single-crystal and powder X-ray diffractions, IR spectroscopy, and elemental and thermogravimetric analyses. Complexes
and
are isotypic, displaying helical chain structures. The fluorescence properties of
and
were investigated. |
|---|---|
| ISSN: | 0932-0776 1865-7117 |
| DOI: | 10.1515/znb-2015-0086 |