mer-Triammine Trifluorido Iron(III), mer-[FeF3(NH3)3]
Metal fluorides are scarcely soluble in liquid ammonia, and their ammine complexes are rare. The synthesis and crystal structure of the first ammine complex of an iron fluoride, the mer-triammine trifluorido iron(III), mer-[FeF (NH ], is presented. The compound crystallizes in the form of colorless,...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2011-08, Vol.66 (8), p.865-867 |
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| container_issue | 8 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 66 |
| creator | Baer, Sebastian A. Kraus, Florian |
| description | Metal fluorides are scarcely soluble in liquid ammonia, and their ammine complexes are rare. The synthesis and crystal structure of the first ammine complex of an iron fluoride, the mer-triammine trifluorido iron(III), mer-[FeF
(NH
], is presented. The compound crystallizes in the form of colorless, needle-shaped single crystals in the monoclinic space group P2
with Z = 4. The molecules are interconnected by strong N-H· · ·F hydrogen bonds. |
| doi_str_mv | 10.1515/znb-2011-0814 |
| format | Article |
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(NH
], is presented. The compound crystallizes in the form of colorless, needle-shaped single crystals in the monoclinic space group P2
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(NH
], is presented. The compound crystallizes in the form of colorless, needle-shaped single crystals in the monoclinic space group P2
with Z = 4. The molecules are interconnected by strong N-H· · ·F hydrogen bonds.</description><subject>Ammine</subject><subject>Crystal Structure</subject><subject>Fluoride</subject><subject>Iron</subject><subject>Liquid Ammonia</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNptkE1LAzEQhoMouFaP3ntswWiy-drgSYprF4pe6kkkZJOJbNkPyVqk_nqz1KPMYd7DM8M8g9A1JbdUUHH309c4J5RiUlB-gjJaSIEVpeoUZUSzHBOl5Dm6GMcdIVRzTjIkOoh4GxvbdU0P85RCux9i44d5FYd-UVXV8mY-QW8llGzxvGZL9n6JzoJtR7j66zP0Wj5uV2u8eXmqVg8b7HLOBPa5ZsQ6KVThNQ-eAZUilbNKcw-yDrzONZeOcgCpnQogbcilJrUG8I7NED7udXEYxwjBfMams_FgKDGTs0nOZnI2k3Pi74_8t22_IHr4iPtDCmY37GOfLv1_TsoivYr9AmAGW2Y</recordid><startdate>20110801</startdate><enddate>20110801</enddate><creator>Baer, Sebastian A.</creator><creator>Kraus, Florian</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20110801</creationdate><title>mer-Triammine Trifluorido Iron(III), mer-[FeF3(NH3)3]</title><author>Baer, Sebastian A. ; Kraus, Florian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2435-d2930ac6578d94fd3e165656ca794de6bf4b2946c14ee69c7fe6af2690b9eedc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Ammine</topic><topic>Crystal Structure</topic><topic>Fluoride</topic><topic>Iron</topic><topic>Liquid Ammonia</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baer, Sebastian A.</creatorcontrib><creatorcontrib>Kraus, Florian</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baer, Sebastian A.</au><au>Kraus, Florian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>mer-Triammine Trifluorido Iron(III), mer-[FeF3(NH3)3]</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>2011-08-01</date><risdate>2011</risdate><volume>66</volume><issue>8</issue><spage>865</spage><epage>867</epage><pages>865-867</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>Metal fluorides are scarcely soluble in liquid ammonia, and their ammine complexes are rare. The synthesis and crystal structure of the first ammine complex of an iron fluoride, the mer-triammine trifluorido iron(III), mer-[FeF
(NH
], is presented. The compound crystallizes in the form of colorless, needle-shaped single crystals in the monoclinic space group P2
with Z = 4. The molecules are interconnected by strong N-H· · ·F hydrogen bonds.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-2011-0814</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2011-08, Vol.66 (8), p.865-867 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_crossref_primary_10_1515_znb_2011_0814 |
| source | Alma/SFX Local Collection |
| subjects | Ammine Crystal Structure Fluoride Iron Liquid Ammonia |
| title | mer-Triammine Trifluorido Iron(III), mer-[FeF3(NH3)3] |
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