mer-Triammine Trifluorido Iron(III), mer-[FeF3(NH3)3]
Metal fluorides are scarcely soluble in liquid ammonia, and their ammine complexes are rare. The synthesis and crystal structure of the first ammine complex of an iron fluoride, the mer-triammine trifluorido iron(III), mer-[FeF (NH ], is presented. The compound crystallizes in the form of colorless,...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2011-08, Vol.66 (8), p.865-867 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | Metal fluorides are scarcely soluble in liquid ammonia, and their ammine complexes are rare. The synthesis and crystal structure of the first ammine complex of an iron fluoride, the mer-triammine trifluorido iron(III), mer-[FeF
(NH
], is presented. The compound crystallizes in the form of colorless, needle-shaped single crystals in the monoclinic space group P2
with Z = 4. The molecules are interconnected by strong N-H· · ·F hydrogen bonds. |
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| ISSN: | 0932-0776 1865-7117 |
| DOI: | 10.1515/znb-2011-0814 |