Solid-state and Solution Studies on a β-Diketiminate Zinc Hydride Complex

Solid-state and Solution Studies on a β-Diketiminate Zinc Hydride Complex

[MesnacnacZn(μ-H)] (1) was synthesized by reaction of MesnacnacZnI with either an equimolar amount of KNH(iPr)BH or an excess of NaH and characterized by multinuclear NMR and IR spectroscopy as well as X-ray diffraction. Two polymorphs of 1 were found and their structures determined on single crysta...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2009-12, Vol.64 (11), p.1397-1400
Hauptverfasser: Schulz, Stephan, Eisenmann, Tamara, Schuchmann, Daniella, Bolte, Michael, Kirchner, Michael, Boese, Roland, Spielmann, Jan, Harder, Sjoerd
Format: Artikel
Sprache:eng
Schlagworte:
Polymorphs
X-Ray Structure
Zinc
β -Diketiminate
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Zusammenfassung:[MesnacnacZn(μ-H)] (1) was synthesized by reaction of MesnacnacZnI with either an equimolar amount of KNH(iPr)BH or an excess of NaH and characterized by multinuclear NMR and IR spectroscopy as well as X-ray diffraction. Two polymorphs of 1 were found and their structures determined on single crystals
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-2009-11-1221