Metallkomplexe mit biologisch wichtigen Liganden, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylat-Rhodium-Komplexe / Metal Complexes of Biologically Important Ligands, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylate-Rhodium Complexes

Metallkomplexe mit biologisch wichtigen Liganden, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylat-Rhodium-Komplexe / Metal Complexes of Biologically Important Ligands, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylate-Rhodium Complexes

The reactions of [(η -C Rh-μ-Cl] with the anions of α-amino acids (glycine, L-alanine, L-valine, L-isoleucine, L-proline, L-phenylalanine, L-phenylglycine, L-thyrosine) afford the N,O-chelates (η -C Rh(α-amino carboxylate). For complex (η -C Rh(glycinate) dynamic behaviour in solution could be obser...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2002-07, Vol.57 (7), p.810-818
Hauptverfasser: Ponikwar, Walter, Mayer, Peter, Beck, Wolfgang
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Sprache:eng
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Allyl
Rhodium Complexes
α-Amino Acids
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container_title Zeitschrift für Naturforschung. B, A journal of chemical sciences
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creator Ponikwar, Walter
Mayer, Peter
Beck, Wolfgang
description The reactions of [(η -C Rh-μ-Cl] with the anions of α-amino acids (glycine, L-alanine, L-valine, L-isoleucine, L-proline, L-phenylalanine, L-phenylglycine, L-thyrosine) afford the N,O-chelates (η -C Rh(α-amino carboxylate). For complex (η -C Rh(glycinate) dynamic behaviour in solution could be observed by H NMR. The structure of (η -C Rh(L-prolinate) was determined by X-ray diffraction.
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subjects Allyl
Rhodium Complexes
α-Amino Acids
title Metallkomplexe mit biologisch wichtigen Liganden, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylat-Rhodium-Komplexe / Metal Complexes of Biologically Important Ligands, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylate-Rhodium Complexes
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