Metallkomplexe mit biologisch wichtigen Liganden, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylat-Rhodium-Komplexe / Metal Complexes of Biologically Important Ligands, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylate-Rhodium Complexes

The reactions of [(η -C Rh-μ-Cl] with the anions of α-amino acids (glycine, L-alanine, L-valine, L-isoleucine, L-proline, L-phenylalanine, L-phenylglycine, L-thyrosine) afford the N,O-chelates (η -C Rh(α-amino carboxylate). For complex (η -C Rh(glycinate) dynamic behaviour in solution could be observed by H NMR. The structure of (η -C Rh(L-prolinate) was determined by X-ray diffraction.