peri-Interactions in Naphthalenes, 5 [1]. On the Impact of peri-Stress and Trityl-Stress upon the Length of N+-C Bonds in 1-Azonia-acenaphthene Cations

peri-Interactions in Naphthalenes, 5 [1]. On the Impact of peri-Stress and Trityl-Stress upon the Length of N+-C Bonds in 1-Azonia-acenaphthene Cations

In the 1-azonia-acenaphthene salts 6b and 9, the N -C bond is modestly elongated. While no clear-cut influence of the peri-stress is obvious, incorporation of C in a triarylmethyl structure has a bond-lengthening effect. However, the stretching forces are insufficient to restore the ideal geometry o...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2001-11, Vol.56 (11), p.1109-1116
Hauptverfasser: Dyker, Gerald, Hagel, Marcel, Henkel, Gerald, Köckerling, Martin, Näther, Christian, Petersen, Sönke, Schiemenzd, Günter Paulus
Format: Artikel
Sprache:eng
Schlagworte:
peri-Naphthalenes
Steric Effects
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In the 1-azonia-acenaphthene salts 6b and 9, the N -C bond is modestly elongated. While no clear-cut influence of the peri-stress is obvious, incorporation of C in a triarylmethyl structure has a bond-lengthening effect. However, the stretching forces are insufficient to restore the ideal geometry of the naphthalene skeleton.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-2001-1103