N-Boryl-Substituted Bis(amino)stannylenes and -plumbylenes
Two equivalents of N-lithio-N-trimethylsilyl-amino-9-borabicyclo[3.3.1]nonane (1) react with tin and lead dichloride by salt elimination to give the corresponding bis(amino)stannylene 2 and -plumbylene 3, respectively. The compounds 2 and 3 are monomers in solution and were characterized by H, C, N,...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1997-08, Vol.52 (8), p.947-950 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | Two equivalents of N-lithio-N-trimethylsilyl-amino-9-borabicyclo[3.3.1]nonane (1) react with tin and lead dichloride by salt elimination to give the corresponding bis(amino)stannylene 2 and -plumbylene 3, respectively. The compounds 2 and 3 are monomers in solution and were characterized by
H,
C,
N,
Si,
Sn and
Pb NMR spectroscopy. |
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| ISSN: | 0932-0776 1865-7117 |
| DOI: | 10.1515/znb-1997-0811 |