Novel Electrochemically Derived Dimers of Methylated Uracils

Novel Electrochemically Derived Dimers of Methylated Uracils

Electrolysis of acetic acid/sodium acetate solutions of N-methylated uracils results in the formation of 5-substituted methyl and acethoxy derivatives. Electrolysis of trifluoroacetic acid/potassium trifluoroacetate solutions of N-1-and N-3-methylated uracils provided, be­ sides 5-trifluoromethyl de...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1997-06, Vol.52 (6), p.742-748
Hauptverfasser: Bojarska, Elżbieta, Kamiński, Jarosław, Stolarski, Ryszard, Kazimierczuk, Zygmunt
Format: Artikel
Sprache:eng
Schlagworte:
Electrochemical Oxidation Electrochemical Trifluoromethylation
Electrolysis
Radical Substitution
Uracil Dimers of N-C
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Zusammenfassung:Electrolysis of acetic acid/sodium acetate solutions of N-methylated uracils results in the formation of 5-substituted methyl and acethoxy derivatives. Electrolysis of trifluoroacetic acid/potassium trifluoroacetate solutions of N-1-and N-3-methylated uracils provided, be­ sides 5-trifluoromethyl derivatives, novel N-C uracil dimers. In the case of 1,3-dimethyluracil in trifluoroacetic acid. N-l demethylathion was also observed.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1997-0612