A Structural Study on Indium Tris-thiocarbamates
Indium tris(thiocarbamates) In(S CN Pr (1), In(SOCN Pr (2) and In(S CNC (3) have been synthesized and characterized. Variable temperature H NMR spectra of 1 and 2 are reported. The X-ray molecular structures of 1 and 3 are found to be quite similar; the symmetry of the In(S C) unit in 3 is close to...
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Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1994-02, Vol.49 (2), p.193-198 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Indium tris(thiocarbamates) In(S
CN
Pr
(1), In(SOCN
Pr
(2) and In(S
CNC
(3) have been synthesized and characterized. Variable temperature
H NMR spectra of 1 and 2 are reported. The X-ray molecular structures of 1 and 3 are found to be quite similar; the symmetry of the In(S
C)
unit in 3 is close to point group D
with small asymmetry in the In-S bonds. |
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ISSN: | 0932-0776 1865-7117 |
DOI: | 10.1515/znb-1994-0207 |