A Structural Study on Indium Tris-thiocarbamates

Indium tris(thiocarbamates) In(S CN Pr (1), In(SOCN Pr (2) and In(S CNC (3) have been synthesized and characterized. Variable temperature H NMR spectra of 1 and 2 are reported. The X-ray molecular structures of 1 and 3 are found to be quite similar; the symmetry of the In(S C) unit in 3 is close to...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1994-02, Vol.49 (2), p.193-198
Hauptverfasser: Bhattacharya, S., Seth, Miss Neena, Gupta, V. D., Nöth, H., Thomann, M.
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Sprache:eng
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Zusammenfassung:Indium tris(thiocarbamates) In(S CN Pr (1), In(SOCN Pr (2) and In(S CNC (3) have been synthesized and characterized. Variable temperature H NMR spectra of 1 and 2 are reported. The X-ray molecular structures of 1 and 3 are found to be quite similar; the symmetry of the In(S C) unit in 3 is close to point group D with small asymmetry in the In-S bonds.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1994-0207