Imine-Enamine Tautomerism -Nucleophilic Reactions of Imines

Imine-Enamine Tautomerism -Nucleophilic Reactions of Imines

A reinvestigation of the reactivity of N-isopropylidene cyclohexylamine to methyl acrylate by GC-MS analysis has shown that the major product is the β-aminoester (9) formed by the N-alkylation of cyclohexylamine which may be generated by a dimerisation-elimination sequence. A number of other product...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1982-06, Vol.37 (6), p.757-761
Hauptverfasser: Rahman, Atta-ur, Ahmad, Viqar Uddin, Sultana, Mumtaz, Perveen, Nusrat, Sultana, Nighat
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
Enaminos
Ketimines
Nucleophiles
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Zusammenfassung:A reinvestigation of the reactivity of N-isopropylidene cyclohexylamine to methyl acrylate by GC-MS analysis has shown that the major product is the β-aminoester (9) formed by the N-alkylation of cyclohexylamine which may be generated by a dimerisation-elimination sequence. A number of other products resulting from N-and C-alkylation of the ketimine have been identified.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1982-0616