Die Kristallstruktur des Bis (1,2-diaminoethan)-kupfer(II)-diiodocuprats (I), [Cu(H2NCH2CH2NH2)2(CuI4/2)2] / The Crystal Structure of [Cu(H2NCH2CH2NH2)2(CuI4/2)2]

Die Kristallstruktur des Bis (1,2-diaminoethan)-kupfer(II)-diiodocuprats (I), [Cu(H2NCH2CH2NH2)2(CuI4/2)2] / The Crystal Structure of [Cu(H2NCH2CH2NH2)2(CuI4/2)2]

The copper complex [Cu(en) (Cu I ] crystallizes monoclinically in the space group C2/m with a = 1039.4(4) pm, b = 1337.5(3) pm, c = 656.7(2) pm, β = 117.51(2)° and Z = 2 formula units. The crystal structure is built up by cations [Cu(II)(en) and anionic chains of edge-sharing tetrahedra [Cu(I) I whi...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1980-10, Vol.35 (10), p.1319-1321
Hauptverfasser: Freckmann, Bernhard, Tebbe, Karl-Friedrich
Format: Artikel
Sprache:eng
Schlagworte:
Crystal Structure
Mixed Valence Copper Complex
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Zusammenfassung:The copper complex [Cu(en) (Cu I ] crystallizes monoclinically in the space group C2/m with a = 1039.4(4) pm, b = 1337.5(3) pm, c = 656.7(2) pm, β = 117.51(2)° and Z = 2 formula units. The crystal structure is built up by cations [Cu(II)(en) and anionic chains of edge-sharing tetrahedra [Cu(I) I which are weakly connected by a short distance d(Cu(II) ··· I) = 340.2 pm.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1980-1030