Fluorierung von Platin(IV)amminkomplexen in wäßriger Lösung / Fluorination of Ammine Complexes of Platinum(IV) in Aqueous Solution
Unlike chlorination fluorination of ammine complexes of platinum(IV) in aqueous solution does not lead to haloamido complexes. Instead, the triammine complexes [Pt(NH Cl ]Cl and [Pt(NH (NCl Cl]Cl yield no definite main product, and the tetrammine and pentammine complexes trans-[Pt(NH Cl ]Cl , [Pt(NH...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1978-12, Vol.33 (12), p.1561-1562 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Unlike chlorination fluorination of ammine complexes of platinum(IV) in aqueous solution does not lead to haloamido complexes. Instead, the triammine complexes [Pt(NH
Cl
]Cl and [Pt(NH
(NCl
Cl]Cl yield no definite main product, and the tetrammine and pentammine complexes trans-[Pt(NH
Cl
]Cl
, [Pt(NH
(NCl
)Cl]Cl
, [Pt(NH
Cl]Cl
, and [Pt(NH
(OH)]Cl
form the sparingly soluble complex trans -[Pt (NH
Cl
](H
· 2H
O as the main product. |
|---|---|
| ISSN: | 0932-0776 1865-7117 |
| DOI: | 10.1515/znb-1978-1241 |