Syntheses and Structures of Keggin-Type Polyoxometalate Crystals Hybridized with a Polymerizable Ionic-Liquid

Keggin-type polyoxometalate clusters were successfully hybridized with a polymerizable ionic-liquid having methacryloyl group and imidazolium moieties (denoted as MAImC1). Metatungstate ([H2W12O40]6−, H2W12) and dodecamolybdophosphate ([PMo12O40]3−, PMo12) anions were firstly employed to obtain inor...

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Veröffentlicht in:Transactions of the Materials Research Society of Japan 2021/03/01, Vol.46(1), pp.15-18
Hauptverfasser: Otobe, Saki, Kiyota, Yoshiki, Kojima, Tatsuhiro, Oda, Yoshiki, Koguchi, Shinichi, Okamura, Yosuke, Higuchi, Masashi, Kawano, Masaki, Nagase, Yu, Ito, Takeru
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Sprache:eng
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Zusammenfassung:Keggin-type polyoxometalate clusters were successfully hybridized with a polymerizable ionic-liquid having methacryloyl group and imidazolium moieties (denoted as MAImC1). Metatungstate ([H2W12O40]6−, H2W12) and dodecamolybdophosphate ([PMo12O40]3−, PMo12) anions were firstly employed to obtain inorganic-organic hybrid crystals. Their compositions and structures were clearly revealed by single crystal structure analyses.
ISSN:1382-3469
2188-1650
DOI:10.14723/tmrsj.46.15