Electron Impact-Induced Fragmentation of the Sesquiterpene Germacrene D
The sesquiterpene germacrene D and two deuterium-labeled isotopomers were analyzed by enantio-multidimensional gas chromatography with tandem mass spectrometry in order to investigate mass spectral fragmentation mechanisms. The deuterated analogues were derived from in vivo feeding experiments with...
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| Veröffentlicht in: | European journal of mass spectrometry (Chichester, England) England), 2001-12, Vol.7 (6), p.503-508 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The sesquiterpene germacrene D and two deuterium-labeled isotopomers were analyzed by enantio-multidimensional gas chromatography with tandem mass spectrometry in order to investigate mass spectral fragmentation mechanisms. The deuterated analogues were derived from in vivo feeding experiments with 1-[5,5-D2]deoxy-D-xylulose-5-phosphate using intact plant material of Solidago canadensis and were formed by biosynthesis via the methylerythritol phosphate pathway. |
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| ISSN: | 1469-0667 1751-6838 |
| DOI: | 10.1255/ejms.466 |