Reaction of Substituted Benzenes and Chloral. VII: Reaction of o-Acetotoluidide and Chloral
The product obtained from the reaction of o-acetotoluidide and chloral in conc. sulfuric acid failed to be crystallized but its reduction with zinc dust and glacial acetic acid gave crystals of m. p. 156°. Its structure was clarified by the formation of 3-acetamido-4-methylbenzoic acid by its dehydr...
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| Veröffentlicht in: | YAKUGAKU ZASSHI 1957/09/25, Vol.77(9), pp.1048-1049 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng ; jpn |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The product obtained from the reaction of o-acetotoluidide and chloral in conc. sulfuric acid failed to be crystallized but its reduction with zinc dust and glacial acetic acid gave crystals of m. p. 156°. Its structure was clarified by the formation of 3-acetamido-4-methylbenzoic acid by its dehydrochlorination and oxidation. |
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| ISSN: | 0031-6903 1347-5231 |
| DOI: | 10.1248/yakushi1947.77.9_1048 |