TRIFLUOROMETHYLATION OF CHIRAL ALDEHYDE AND SYNTHESIS OF 6-DEOXY-6, 6, 6-TRIFLUOROHEXOSES

Trifluoromethylation of chiral aldehyde derived from suger was efficiently carried out by a modification of the reported procedure. The preparation of 6, 6, 6-trifluoro-L-daunosamine was also achieved by using (2S, 3R)-4, 4, 4-trifluorobutane-1, 2, 3-triol derivative.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical & pharmaceutical bulletin 1991/09/25, Vol.39(9), pp.2459-2461
Hauptverfasser:	HANZAWA, Yuji, UDA, Jun-ichiro, KOBAYASHI, Yoshiro, ISHIDO, Yoshiharu, TAGUCHI, Takeo, SHIRO, Motoo
Format:	Artikel
Sprache:	eng
Schlagworte:	6, 6, 6-trifluoro-L-daunosamine 6-deoxy-6, 6, 6-trifluorohexose Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Chemistry Exact sciences and technology Grifluoromethylation Organic chemistry Preparations and properties slow addition ultrasound
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Beschreibung
Zusammenfassung:	Trifluoromethylation of chiral aldehyde derived from suger was efficiently carried out by a modification of the reported procedure. The preparation of 6, 6, 6-trifluoro-L-daunosamine was also achieved by using (2S, 3R)-4, 4, 4-trifluorobutane-1, 2, 3-triol derivative.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.39.2459