Simple Synthesis of trans-3, 4-Bis(methoxycarbonylmethyl)cyclopentanone

A simple procedure is described for the synthesis of trans-3, 4-bis(methoxycarbonylmethyl)-cyclopentanone (4), starting with dimethyl muconate or dimethyl 3, 4-dibromoadipate and dimethyl sodiomalonate.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical & pharmaceutical bulletin 1986/02/25, Vol.34(2), pp.873-875
Hauptverfasser:	AMEMIYA, SHIGEO, KOJIMA, KOICHI, OKANO, KOUJI, FUNAKOSHI, KAZUHISA, SUEMUNE, HIROSHI, SAKAI, KIYOSHI
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Dieckmann condensation Exact sciences and technology Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A simple procedure is described for the synthesis of trans-3, 4-bis(methoxycarbonylmethyl)-cyclopentanone (4), starting with dimethyl muconate or dimethyl 3, 4-dibromoadipate and dimethyl sodiomalonate.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.34.873