ABSOLUTE CONFIGURATIONS OF REHMAIONOSIDES A, B, AND C AND REHMAPICROSIDE THREE NEW IONONE GLUCOSIDES AND A NEW MONOTERPENE GLUCOSIDE FROM REHMANNIAE RADIX

Three new ionone glucosides, rehmaionosides A (1__∼), B (2__∼), and C (3__∼), and a new monoterpene glucoside rehmapicroside (4__∼), were isolated from Chinese Rehmanniae Radix, the dried root of Rehmannia glutinosa L(ibosch)___=.[kan-jio (in Japanese) from China]. Their absolute configurations were...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1986/05/25, Vol.34(5), pp.2294-2297
Hauptverfasser: Yoshikawa, Masayuki, Fukuda, Youichi, Taniyama, Toshio, Cha, Bae Cheon, Kitagawa, Isao
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Sprache:eng
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Zusammenfassung:Three new ionone glucosides, rehmaionosides A (1__∼), B (2__∼), and C (3__∼), and a new monoterpene glucoside rehmapicroside (4__∼), were isolated from Chinese Rehmanniae Radix, the dried root of Rehmannia glutinosa L(ibosch)___=.[kan-jio (in Japanese) from China]. Their absolute configurations were determined on the basis of chemical and physicochemical evidence which included the application of the exciton chirality method for allylic benzoyl derivatives.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.34.2294