TOTAL SYNTHESIS OF (±)-PENTALENENE
(±)-Pentalenene, the least oxidized triquinane sesquiterpene, was totally synthesized starting from 4, 4-dimethyl-2-cyclopenten-1-one via a regioselective C2-C8 bond opening of the tricyclo[3.3.0.02, 8]octan-3-one intermediate.
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Veröffentlicht in: | Chemical & pharmaceutical bulletin 1986/05/25, Vol.34(5), pp.2268-2271 |
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container_title | Chemical & pharmaceutical bulletin |
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creator | Imanishi, Takeshi Ninbari, Fusako Yamashita, Masayuki Iwata, Chuzo |
description | (±)-Pentalenene, the least oxidized triquinane sesquiterpene, was totally synthesized starting from 4, 4-dimethyl-2-cyclopenten-1-one via a regioselective C2-C8 bond opening of the tricyclo[3.3.0.02, 8]octan-3-one intermediate. |
doi_str_mv | 10.1248/cpb.34.2268 |
format | Article |
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Bull.</addtitle><description>(±)-Pentalenene, the least oxidized triquinane sesquiterpene, was totally synthesized starting from 4, 4-dimethyl-2-cyclopenten-1-one via a regioselective C2-C8 bond opening of the tricyclo[3.3.0.02, 8]octan-3-one intermediate.</description><subject>Alicyclic compounds, terpenoids, prostaglandins, steroids</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><subject>Preparations and properties</subject><subject>Terpenoids</subject><subject>total synthesis</subject><issn>0009-2363</issn><issn>1347-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1986</creationdate><recordtype>article</recordtype><recordid>eNpFj8tKA0EQRRtRMEZX_kBAF4rM2O_HMiQTEwiJkHHhqqnp6daEGEN3Nn6Wv-CXOcNIpKBqcU8duAhdE5wTyvWj21c54zmlUp-gHmFcZYJSdop6GGOTUSbZObpIaYMxFVixHropl-VwPli9LsppsZqtBsvJ4O7n-z57LhZNUCyauURnAbbJX_3dPnqZFOVoms2XT7PRcJ45IfghAxkoKKm58ZV0mnHjcK05eAOBe1PXRFe1YMpLELpyARwBTYxTRJHga8n66KHzuviZUvTB7uP6A-KXJdi2_WzTzzJu234NfdvRe0gOtiHCzq3T8UUZgQ0RDTbusE06wJs_5hAPa7f1rZIYoVut6FZr_4_fIVq_Y7-0RmTo</recordid><startdate>1986</startdate><enddate>1986</enddate><creator>Imanishi, Takeshi</creator><creator>Ninbari, Fusako</creator><creator>Yamashita, Masayuki</creator><creator>Iwata, Chuzo</creator><general>The Pharmaceutical Society of Japan</general><general>Maruzen</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1986</creationdate><title>TOTAL SYNTHESIS OF (±)-PENTALENENE</title><author>Imanishi, Takeshi ; Ninbari, Fusako ; Yamashita, Masayuki ; Iwata, Chuzo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c554t-a6f2a76849eb6c8349c0d84ae9af4e9dd18bd537e6a58bcfac1a819c7171fed63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1986</creationdate><topic>Alicyclic compounds, terpenoids, prostaglandins, steroids</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><topic>Preparations and properties</topic><topic>Terpenoids</topic><topic>total synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Imanishi, Takeshi</creatorcontrib><creatorcontrib>Ninbari, Fusako</creatorcontrib><creatorcontrib>Yamashita, Masayuki</creatorcontrib><creatorcontrib>Iwata, Chuzo</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Chemical & pharmaceutical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Imanishi, Takeshi</au><au>Ninbari, Fusako</au><au>Yamashita, Masayuki</au><au>Iwata, Chuzo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>TOTAL SYNTHESIS OF (±)-PENTALENENE</atitle><jtitle>Chemical & pharmaceutical bulletin</jtitle><addtitle>Chem. Pharm. Bull.</addtitle><date>1986</date><risdate>1986</risdate><volume>34</volume><issue>5</issue><spage>2268</spage><epage>2271</epage><pages>2268-2271</pages><issn>0009-2363</issn><eissn>1347-5223</eissn><coden>CPBTAL</coden><abstract>(±)-Pentalenene, the least oxidized triquinane sesquiterpene, was totally synthesized starting from 4, 4-dimethyl-2-cyclopenten-1-one via a regioselective C2-C8 bond opening of the tricyclo[3.3.0.02, 8]octan-3-one intermediate.</abstract><cop>Tokyo</cop><pub>The Pharmaceutical Society of Japan</pub><doi>10.1248/cpb.34.2268</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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source | J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry |
subjects | Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Organic chemistry Preparations and properties Terpenoids total synthesis |
title | TOTAL SYNTHESIS OF (±)-PENTALENENE |
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