TOTAL SYNTHESIS OF (±)-PENTALENENE

(±)-Pentalenene, the least oxidized triquinane sesquiterpene, was totally synthesized starting from 4, 4-dimethyl-2-cyclopenten-1-one via a regioselective C2-C8 bond opening of the tricyclo[3.3.0.02, 8]octan-3-one intermediate.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical & pharmaceutical bulletin 1986/05/25, Vol.34(5), pp.2268-2271
Hauptverfasser:	Imanishi, Takeshi, Ninbari, Fusako, Yamashita, Masayuki, Iwata, Chuzo
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology Organic chemistry Preparations and properties Terpenoids total synthesis
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Beschreibung
Zusammenfassung:	(±)-Pentalenene, the least oxidized triquinane sesquiterpene, was totally synthesized starting from 4, 4-dimethyl-2-cyclopenten-1-one via a regioselective C2-C8 bond opening of the tricyclo[3.3.0.02, 8]octan-3-one intermediate.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.34.2268