Structure of menisporphine: a new type of isoquinoline alkaloid

The structure of an unknown yellow base from Menisperum dauricum DC. (Menispermaceae) was determined to be 5, 6, 9-trimethoxy-7H-dibenzo [de, h] quinolin-7-one (1) by spectral data and total synthesis. It was named menisporphine and the skeletal name"oxoisoaporphine"was proposed for this n...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1982/07/25, Vol.30(7), pp.2659-2660
Hauptverfasser: Kunitomo, J, Satoh, M
Format: Artikel
Sprache:eng
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Zusammenfassung:The structure of an unknown yellow base from Menisperum dauricum DC. (Menispermaceae) was determined to be 5, 6, 9-trimethoxy-7H-dibenzo [de, h] quinolin-7-one (1) by spectral data and total synthesis. It was named menisporphine and the skeletal name"oxoisoaporphine"was proposed for this new type of alkaloid. The biosynthesis route of oxoisoaporphine-type alkaloids in plants is suggested.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.30.2659