Photostability of Water-dispersible CdTe Quantum Dots: Capping Ligands and Oxygen

Here we report the effect of various capping ligands on the optical properties and photostability of CdTe quantum dots in aqueous solutions. Ligand exchange procedure is used to prepare water dispersive CdTe nanocrystals capped with aminoethanethiol, 3-mercaptopropionic and dihydrolipoic acids. The...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2010-06, Vol.39 (6), p.654-656
Hauptverfasser: Emin, Saim, Loukanov, Alexandre, Wakasa, Masanobu, Nakabayashi, Seiichiro, Kaneko, Yasuko
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Here we report the effect of various capping ligands on the optical properties and photostability of CdTe quantum dots in aqueous solutions. Ligand exchange procedure is used to prepare water dispersive CdTe nanocrystals capped with aminoethanethiol, 3-mercaptopropionic and dihydrolipoic acids. The dynamics of photoexcited states is examined by transient photoluminescent spectroscopy. Our results demonstrate that the luminescence intensity of water-dispersible CdTe quantum dots is strongly influenced by molecular oxygen under light irradiation.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2010.654