Fluoro-substituted Phenyleneethynylenes: Acetylenic n-Type Organic Semiconductors

Fluoro-substituted phenyleneethynylenes are synthesized by Sonogashira coupling and acetylide-nucleophilic substitution of fluorobenzenes. Fluoro-substitution of benzenes enables deep LUMO potential, and CF3-substitution provides high electron mobility in deposited film (μ = 5.5 × 10−2 cm2 V−1 s−1)....

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Veröffentlicht in:	Chemistry letters 2010-12, Vol.39 (12), p.1300-1302
Hauptverfasser:	Matsuo, Daisuke, Yang, Xin, Hamada, Akiko, Morimoto, Kyo, Kato, Takuji, Yahiro, Masayuki, Adachi, Chihaya, Orita, Akihiro, Otera, Junzo
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description	Fluoro-substituted phenyleneethynylenes are synthesized by Sonogashira coupling and acetylide-nucleophilic substitution of fluorobenzenes. Fluoro-substitution of benzenes enables deep LUMO potential, and CF3-substitution provides high electron mobility in deposited film (μ = 5.5 × 10−2 cm2 V−1 s−1).
doi_str_mv	10.1246/cl.2010.1300
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source	Oxford University Press Journals All Titles (1996-Current)
title	Fluoro-substituted Phenyleneethynylenes: Acetylenic n-Type Organic Semiconductors
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