Fluoro-substituted Phenyleneethynylenes: Acetylenic n-Type Organic Semiconductors

Fluoro-substituted Phenyleneethynylenes: Acetylenic n-Type Organic Semiconductors

Fluoro-substituted phenyleneethynylenes are synthesized by Sonogashira coupling and acetylide-nucleophilic substitution of fluorobenzenes. Fluoro-substitution of benzenes enables deep LUMO potential, and CF3-substitution provides high electron mobility in deposited film (μ = 5.5 × 10−2 cm2 V−1 s−1)....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2010-12, Vol.39 (12), p.1300-1302
Hauptverfasser: Matsuo, Daisuke, Yang, Xin, Hamada, Akiko, Morimoto, Kyo, Kato, Takuji, Yahiro, Masayuki, Adachi, Chihaya, Orita, Akihiro, Otera, Junzo
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Fluoro-substituted phenyleneethynylenes are synthesized by Sonogashira coupling and acetylide-nucleophilic substitution of fluorobenzenes. Fluoro-substitution of benzenes enables deep LUMO potential, and CF3-substitution provides high electron mobility in deposited film (μ = 5.5 × 10−2 cm2 V−1 s−1).
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2010.1300