Extraction of Actinides and Fission Products by the New Ligand, N,N,N′,N′-Tetraoctyl-3,6-dioxaoctanediamide
New reagent, N,N,N′,N′-tetraoctyl-3,6-dioxaoctanediamide (DOODA-C8), was synthesized and examined for the actinide and fission product extractions. Extraction from nitric acid to n-dodecane was studied and it was found that DOODA-C8 can extract UVI, PuIV, AmIII, lanthanides (Ln)III, and TcVII. The D...
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Veröffentlicht in: | Chemistry letters 2009-06, Vol.38 (6), p.630-631 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | New reagent, N,N,N′,N′-tetraoctyl-3,6-dioxaoctanediamide (DOODA-C8), was synthesized and examined for the actinide and fission product extractions. Extraction from nitric acid to n-dodecane was studied and it was found that DOODA-C8 can extract UVI, PuIV, AmIII, lanthanides (Ln)III, and TcVII. The D values of FeIII, PdII, and ZrIV indicate weak complexation with DOODA-C8. The aqueous conditions for the partitioning process can be prepared in the absence of masking agents. |
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ISSN: | 0366-7022 1348-0715 |
DOI: | 10.1246/cl.2009.630 |