Platinum(II)-catalyzed Acetal–Ene Reaction: Easy Access to Homoallylic Ethers

Platinum(II)-catalyzed Acetal–Ene Reaction: Easy Access to Homoallylic Ethers

Catalytic use of PtCl2 and AgX (X=OTf and SbF6) has been found to effectively promote the intermolecular ene reaction of acetals and the tandem acetalization–ene reaction of aldehydes under solvent-free conditions.

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Veröffentlicht in:Chemistry letters 2009-12, Vol.38 (12), p.1204-1205
Hauptverfasser: Miura, Katsukiyo, Izumi, Hiroyuki, Kinoshita, Hidenori, Ichikawa, Junji, Hosomi, Akira
Format: Artikel
Sprache:eng
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Zusammenfassung:Catalytic use of PtCl2 and AgX (X=OTf and SbF6) has been found to effectively promote the intermolecular ene reaction of acetals and the tandem acetalization–ene reaction of aldehydes under solvent-free conditions.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2009.1204