TTF–Cytosine Dyad as an Electron-donor Molecule Having Proton-accepting Ability: Formation of Hemiprotonated Cytosine Dimer in I3− Salt

TTF–Cytosine Dyad as an Electron-donor Molecule Having Proton-accepting Ability: Formation of Hemiprotonated Cytosine Dimer in I3− Salt

A tetrathiafulvalene (TTF) derivative with a cytosine moiety was designed and synthesized as a bi-functional molecule with both electron-donating and proton-accepting abilities. In the crystal of I3− salt, TTF–cytosine dyad formed a hemiprotonated dimer through triple hydrogen-bonds with radical cat...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2007-09, Vol.36 (9), p.1102-1103
Hauptverfasser: Miyazaki, Eigo, Morita, Yasushi, Yakiyama, Yumi, Maki, Suguru, Umemoto, Yoshikazu, Ohmoto, Makoto, Nakasuji, Kazuhiro
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A tetrathiafulvalene (TTF) derivative with a cytosine moiety was designed and synthesized as a bi-functional molecule with both electron-donating and proton-accepting abilities. In the crystal of I3− salt, TTF–cytosine dyad formed a hemiprotonated dimer through triple hydrogen-bonds with radical cationic state of the TTF moieties.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2007.1102