Beneficial Effect of TMSCl in the Lewis Acid-mediated Carboxylation of Aromatic Compounds with Carbon Dioxide

Beneficial Effect of TMSCl in the Lewis Acid-mediated Carboxylation of Aromatic Compounds with Carbon Dioxide

The Lewis acid-mediated carboxylation of aromatic compounds with CO2 is significantly promoted by the addition of a large excess of chlorotrimethylsilane (TMSCl) to give arylcarboxylic acids in good to excellent yields.

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Veröffentlicht in:Chemistry letters 2006-07, Vol.35 (7), p.820-821
Hauptverfasser: Nemoto, Koji, Yoshida, Hiroki, Suzuki, Yutaka, Morohashi, Naoya, Hattori, Tetsutaro
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container_end_page 821
container_issue 7
container_start_page 820
container_title Chemistry letters
container_volume 35
creator Nemoto, Koji
Yoshida, Hiroki
Suzuki, Yutaka
Morohashi, Naoya
Hattori, Tetsutaro
description The Lewis acid-mediated carboxylation of aromatic compounds with CO2 is significantly promoted by the addition of a large excess of chlorotrimethylsilane (TMSCl) to give arylcarboxylic acids in good to excellent yields.
doi_str_mv 10.1246/cl.2006.820
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source Oxford University Press Journals All Titles (1996-Current)
title Beneficial Effect of TMSCl in the Lewis Acid-mediated Carboxylation of Aromatic Compounds with Carbon Dioxide
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