Beneficial Effect of TMSCl in the Lewis Acid-mediated Carboxylation of Aromatic Compounds with Carbon Dioxide

Beneficial Effect of TMSCl in the Lewis Acid-mediated Carboxylation of Aromatic Compounds with Carbon Dioxide

The Lewis acid-mediated carboxylation of aromatic compounds with CO2 is significantly promoted by the addition of a large excess of chlorotrimethylsilane (TMSCl) to give arylcarboxylic acids in good to excellent yields.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry letters 2006-07, Vol.35 (7), p.820-821
Hauptverfasser: Nemoto, Koji, Yoshida, Hiroki, Suzuki, Yutaka, Morohashi, Naoya, Hattori, Tetsutaro
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The Lewis acid-mediated carboxylation of aromatic compounds with CO2 is significantly promoted by the addition of a large excess of chlorotrimethylsilane (TMSCl) to give arylcarboxylic acids in good to excellent yields.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2006.820