A Novel Octanuclear Manganese Cluster with [MnII4(μ4-O)] Core

A Novel Octanuclear Manganese Cluster with [MnII4(μ4-O)] Core

The reaction of MnCl2·4H2O with 2-aminoethanethiol (= Haet) under anaerobic conditions afforded yellow plate crystals of octanuclear manganese complex [Mn4(μ4-O){Mn(aet)3}4]Cl2·MeOH·4H2O. A complex molecule consists of four fac(S)-[Mn(aet)3] units linked to MnII4(μ4-O) core by thiolato bridges. Magn...

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Veröffentlicht in:Chemistry letters 2006-04, Vol.35 (4), p.440-441
Hauptverfasser: Shiga, Takuya, Han, Lingqin, Nihei, Masayuki, Hoshino, Norihisa, Ito, Tasuku, Oshio, Hiroki
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container_end_page 441
container_issue 4
container_start_page 440
container_title Chemistry letters
container_volume 35
creator Shiga, Takuya
Han, Lingqin
Nihei, Masayuki
Hoshino, Norihisa
Ito, Tasuku
Oshio, Hiroki
description The reaction of MnCl2·4H2O with 2-aminoethanethiol (= Haet) under anaerobic conditions afforded yellow plate crystals of octanuclear manganese complex [Mn4(μ4-O){Mn(aet)3}4]Cl2·MeOH·4H2O. A complex molecule consists of four fac(S)-[Mn(aet)3] units linked to MnII4(μ4-O) core by thiolato bridges. Magnetic susceptibility measurements revealed the presence of antiferromagnetic interactions through μ4-oxo and μ2-thiolato bridges.
doi_str_mv 10.1246/cl.2006.440
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source Oxford University Press Journals All Titles (1996-Current)
title A Novel Octanuclear Manganese Cluster with [MnII4(μ4-O)] Core
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