A Novel Octanuclear Manganese Cluster with [MnII4(μ4-O)] Core
The reaction of MnCl2·4H2O with 2-aminoethanethiol (= Haet) under anaerobic conditions afforded yellow plate crystals of octanuclear manganese complex [Mn4(μ4-O){Mn(aet)3}4]Cl2·MeOH·4H2O. A complex molecule consists of four fac(S)-[Mn(aet)3] units linked to MnII4(μ4-O) core by thiolato bridges. Magn...
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| Veröffentlicht in: | Chemistry letters 2006-04, Vol.35 (4), p.440-441 |
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| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The reaction of MnCl2·4H2O with 2-aminoethanethiol (= Haet) under anaerobic conditions afforded yellow plate crystals of octanuclear manganese complex [Mn4(μ4-O){Mn(aet)3}4]Cl2·MeOH·4H2O. A complex molecule consists of four fac(S)-[Mn(aet)3] units linked to MnII4(μ4-O) core by thiolato bridges. Magnetic susceptibility measurements revealed the presence of antiferromagnetic interactions through μ4-oxo and μ2-thiolato bridges. |
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| ISSN: | 0366-7022 1348-0715 |
| DOI: | 10.1246/cl.2006.440 |