Enhanced Reductive Elimination of Dialkylgold(III) Complexes in Water

Enhanced Reductive Elimination of Dialkylgold(III) Complexes in Water

Neutral and cationic dimethyl- or diethylgold(III) complexes having a water-soluble phosphine ligand, AuR2XL and [AuR2L2]X (R = Me or Et; X = Br or I; L = TPPTS, TPPMS, THMP, or DHMPE), are prepared. Reductive elimination involving C–C bond formation at Au(III) in water is faster than those in organ...

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Veröffentlicht in:Chemistry letters 2005-12, Vol.34 (12), p.1704-1705
Hauptverfasser: Komine, Nobuyuki, Ichikawa, Kaoru, Mori, Anna, Hirano, Masafumi, Komiya, Sanshiro
Format: Artikel
Sprache:eng
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Zusammenfassung:Neutral and cationic dimethyl- or diethylgold(III) complexes having a water-soluble phosphine ligand, AuR2XL and [AuR2L2]X (R = Me or Et; X = Br or I; L = TPPTS, TPPMS, THMP, or DHMPE), are prepared. Reductive elimination involving C–C bond formation at Au(III) in water is faster than those in organic solvents.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2005.1704